58-95-7

  • Product Name:D-a Tocopheryl Acetate Oil
  • Molecular Formula:C31H52O3
  • Purity:99%
  • Molecular Weight:472.752
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Product Details

pd_meltingpoint:~25 °C(lit.)

Appearance:off-white crystalline solid

Quality Factory Hot Selling D-a Tocopheryl Acetate Oil 58-95-7 with Fast Shipping

  • Molecular Formula:C31H52O3
  • Molecular Weight:472.752
  • Appearance/Colour:off-white crystalline solid 
  • Melting Point:~25 °C(lit.) 
  • Refractive Index:n20/D 1.496(lit.)  
  • Boiling Point:485.3 °C at 760 mmHg 
  • Flash Point:235.6 °C 
  • PSA:35.53000 
  • Density:0.941 g/cm3 
  • LogP:9.05990 
  • IDLH:2075 

D-alpha-Tocopheryl acetate(Cas 58-95-7) Usage

Air & Water Reactions

D-alpha-Tocopheryl acetate may be sensitive to prolonged exposure to light and air. . Insoluble in water.

Reactivity Profile

An ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Fire Hazard

Flash point data for D-alpha-Tocopheryl acetate are not available. D-alpha-Tocopheryl acetate is probably combustible.

Biochem/physiol Actions

α-Tocopherol acetate or vitamin E-acetate has antioxidant properties and reduces lipid peroxidation. However, vitamin E acetate on pyrolysis leads to the generation of carcinogens like alkenes and benzenes.

Contact allergens

Tocopherol and tocopheryl acetate are used mainly as antioxidants. Tocopheryl acetate, an ester of tocopherol (vitamin E), can induce allergic contact dermatitis.

Safety Profile

When heated to decomposition it emits acrid smoke and irritating fumes.

General Description

Odorless off-white crystals. Darkens at 401° F.

Who Evaluation

Evaluation year: 2010

InChI:InChI=1/C31H52O3.C2H4O2/c1-21(2)13-10-14-22(3)15-11-16-23(4)17-12-19-31(9)20-18-28-26(7)29(33-27(8)32)24(5)25(6)30(28)34-31;1-2(3)4/h21-23H,10-20H2,1-9H3;1H3,(H,3,4)/p-1/t22-,23-,31-;/m1./s1

58-95-7 Relevant articles

Synthesis and characterization of a new acid molten salt and the study of its thermal behavior and catalytic activity in Fischer esterification

Zaharani, Lia,Khaligh, Nader Ghaffari,Johan, Mohd Rafie,Gorjian, Hayedeh

, p. 7081 - 7088 (2021/05/03)

A new acid molten salt was prepared and ...

SYNTHESIS OF CHROMANOL AND 2-METHYL-1,4-NAPHTHOQUINONE DERIVATIVES

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Page/Page column 49-50; 61-62; 68-69, (2020/03/05)

The present invention relates to a proce...

4-Imidazol-1-yl-butane-1-sulfonic acid ionic liquid: Synthesis, structural analysis, physical properties and catalytic application as dual solvent-catalyst

Khaligh, Nader Ghaffari,Mihankhah, Taraneh,Johan, Mohd Rafie,Juan, Joon Ching

, p. 866 - 878 (2019/07/12)

4-Imidazol-1-yl-butane-1-sulfonic acid (...

Method for preparing vitamin E acetate

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Paragraph 0068; 0069; 0070; 0071; 0073, (2019/05/15)

The invention provides a method for prep...

58-95-7 Process route

4-acetoxy-2,3,5-trimethyl-6-butoxymethyl-1-hydroxybenzene
219718-22-6

4-acetoxy-2,3,5-trimethyl-6-butoxymethyl-1-hydroxybenzene

2,6,10,14-tetramethyl-1-pentadecene
2140-82-1,60976-73-0

2,6,10,14-tetramethyl-1-pentadecene

4-acetoxy-2,3,5-trimethylphenol
36592-62-8

4-acetoxy-2,3,5-trimethylphenol

RRR-α-tocopheryl acetate
58-95-7,1406-70-8,54-22-8

RRR-α-tocopheryl acetate

Conditions
Conditions Yield
In butan-1-ol;
 
acetic anhydride
108-24-7

acetic anhydride

Tocopherol
59-02-9,18920-62-2

Tocopherol

RRR-α-tocopheryl acetate
58-95-7,1406-70-8,54-22-8

RRR-α-tocopheryl acetate

Conditions
Conditions Yield
With dmap; In toluene; at 65 ℃; for 5h; Solvent; Large scale;
99.37%
indium(III) triflate; at 25 - 32 ℃; for 4.66667h; Product distribution / selectivity;
97%
11percent Ca +50 percent Na on SiO2 prepared from Ca(OH)2 + Na silicate; at 100 ℃; for 3.5h;
97.7%
With 4-imidazol-1-ylbutane-1-sulfonic acid; at 50 ℃; for 0.5h; Darkness; Inert atmosphere;
80.2%
With pyridine;
 
With acetic acid; In water; at 250 ℃; for 0.00275h; under 37503.8 Torr;
99.0 % Chromat.
With 1-pentyl-3-methylimidazolium nitrate; at 50 ℃; for 3h; Darkness; Inert atmosphere; Green chemistry;
 

58-95-7 Upstream products

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    59-02-9

    Tocopherol

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    186537-57-5

    dl-α-tocopheryl acetate

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    acetic anhydride

  • 59965-06-9
    59965-06-9

    Vitamin E benzyl ether

58-95-7 Downstream products

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    64-19-7

    acetic acid

  • 59-02-9
    59-02-9

    Tocopherol

  • 108-24-7
    108-24-7

    acetic anhydride

  • 7559-04-8
    7559-04-8

    2-[(3R,7R,11R)-3-hydroxy-3,7,11,15-tetramethylhexadecyl]-3,5,6-trimethyl-2,5-cyclohexadiene-1,4-dione

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